Chemical Sciences Seminars

Exploring the Complexity of Supramolecular Interactions at the Liquid-Solid Interface (Part II: Induction and Manipulation)

by Dr. Kunal S. Mali (Katholieke University, Leuven, Belgium)

Friday, April 12, 2013 from to (Asia/Kolkata)
at Colaba Campus ( AG-80 )
TIFR, Colaba Mumbai 400005
Description The second part of my talk will focus on advanced aspects of molecular self-assembly at the liquid-solid interface. Specific examples illustrating pre-programmed formation and manipulation of supramolecular networks will be presented. Following the introduction to the concept of two-dimensional (2D) chirality, strategies for the fabrication of homochiral surfaces with achiral building blocks will be discussed. Using basic principles of molecular self-assembly I will also illustrate how chiral surfaces could be employed for segregating enantiomers from a racemic mixture. Finally, the manipulation of supramolecular networks using external stimuli such as electric fields and shear-flow will be discussed.

Keywords: self-assembly, liquid-solid interface, STM, foldamers, 2D chirality, chiral induction